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I hope you told him urine is not typically supposed to have nitrates in it....
Plants need electrolytes *brawndo*
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Nitrates, sure, but what about electrolytes? *That's* what plants crave!
It's not like the plants are soaking in and retaining urine. They're only soaking in what they need and would be getting elsewhere. As long as you wash them, it'll be good. Though, I'd be more worried about him burning tender plants, he has no way of checking his PH!